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Extra resources for CHEMICAL CONSTITUTION OF THE PROTEINS Part 1
Diaminobutyric Acid. Ornithine or In 1877 Jaffe obtained which he had fed with benzoic acid, dibenzoyl ornithine or ornithuric acid, and from this substance he prepared ornia, from the urine of thine chloride. %-diaminovalerianic Acid.
X COOC H 2 A better + 2 H 2 = HO CH 2 CH(NH 2 )COOH + HOOCC 6 H 5 + C 2 H 5 OH . CH(NH 2 )COOH HO. CH 2 CH(NH 2 )COOH -> . HBr Serine Ethoxylaminopropionic acid Cystine. Under this the compound name of cystic oxide, a new species of urinary calculus, was first described by Wollaston in 1810. Lassaigne it under the same conditions in a dog in 1823. Its presence in the kidney of an ox was shown by Cloetta in 1856, and in the following year Scherer found it in the liver of a patient, who had died of typhoid found fever.
CH 2 CH 2 COOH COOH THE CHEMICAL CONSTITUTION OF UNITS ITS 49 and therefore the SH group was in the /3-position. Further proof was acid given by Friedmann by the synthesis of bromophenylmercapturic with combined was chloride from cysteine. NH 6 2 -> 4 CH 2 Br . Bromodiazobenzene- CH C 6 H 4 Br 2 COOH COOH COOH Cysteine S CH NH -> 2 . Bromophenylcysteine -> 2 . S C 6 H 4 Br . CH 3 COOH Bromophenylmercapturic acid cysteine was first observed by Suter, in 1895, that a-thiolactic acid was formed by the hydrolysis of proteins, and it was constantly obtained by Friedmann.