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By S. Angus

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Extra info for Chlorine. International Thermodynamic Tables of the Fluid State

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5 Density / mol dm -3 Figure 13. Variation of the saturation density near the critical point showing the experimental results of Tsekhanskaya, Polyakova and Kozlovskaya . — n s O O O • ••••••••••• S• • • --~ ~ OO O O 0 O OO O O O 0 0O 0 0 O — o Pellaton s Hengtein etc'. • Giauque and Powell — • Ambrose et ol. (series I) O Ambrose et ol. (series II ) 0 0 0 I 1 1 1 200 250 300 350 O o O O oo o I II 400 T Temperature /E Figure 14. Comparison of experimental vapour pressure data with values calculated from the equation of state.

4 . O ~ 1 03 1 00 200 300 v Estimated data ( series I) 400 500 600 700 800 900 Temperature / K • Estimated data (series fl) . Selected experimental data Figure 12. Distribution of estimated PpT data. 2% of the density. 2% of the density, but it was found essential to include them in the construction of the equation of state, otherwise the saturation curve was poorly represented at low temperatures. 3. 1 Equation of State of the Real Fluid A preliminary equation of state was constructed using a technique described by de Reuck (52 and Armstrong >.

2 Single-Phase Properties Calculated from the Principle of Corresponding States The value of any property for which the principle of corresponding states applies can be calculated, at a specified reduced pressure and reduced temperature, from equation(1) by the substitution of an appropriate dimensionless function for U . 1 Rr T Values of the density were calculated from equation(1) by substituting ZR for UR , where ZR = Z / Zc . The density was calculated at the reduced pressure and temperature of each of the available experimental points for chlorine and compared with the experimental value.

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