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E. Hall; B. McGonigle, Plant Physiol. 2002, 128, 615. R. E. Minto; B. J. Blacklock, Prog. Lipid. Res. 2008, 47, 233. E. B. Cahoon; J. A. Schnurr; E. A. Huffman; R. E. Minto, Plant J. 2003, 34, 671. D. W. Reed; D. R. Polichuk; P. H. Buist; S. J. Ambrose; R. J. Sasata; C. K. Savile; A. R. S. Ross; P. S. Covello, J. Am. Chem. Soc. 2003, 125, 10635. G. Villorbina; S. Rodriguez; F. Camps; G. Fabrias, Insect Biochem. Mol. Biol. 2003, 33, 155. J. L. Abad; S. Rodrı´guez; F. Camps; G. Fabria`s, J. Org. Chem.

Soc. Perkin Trans. 1 1985, 2425. D. W. Reed; C. K. Savile; X. Qui; P. H. Buist; P. S. Covello, Eur. J. Biochem. 2002, 269, 5024. J. L. Abad; F. Camps; G. Fabrias, Angew. Chem. Int. Ed. 2000, 39, 3279. S. Rodriguez; F. Camps; G. Fabrias, J. Org. Chem. 2001, 66, 8052. J. L. Abad; F. Camps; G. Fabrias, Insect Biochem. Mol. Biol. 2001, 31, 799. S. Rodriguez; P. Clapes; F. Camps; G. Fabrias, J. Org. Chem. 2002, 67, 2228. J. L. Abad; F. Camps; G. Fabria`s, J. Am. Chem. Soc. 2007, 129, 15007. M. O. Bagby; C.

This intermediate is metabolized by epoxide hydrolases to yield 5S,6R,15-trihydroxyeicosatetraenoic acid (lipoxin A4, LXA4) or 5S,14R,15-trihydroxyeicosatetraenoic acid (lipoxin B4, LXB4) (Scheme 5). Scheme 5 Biosynthesis of aspirin-triggered lipoxins. AcPGHS-2, ASA-acetylated PGHS-2. Prostaglandin Endoperoxide Synthases 49 Stereochemistry at the 15-position is simply determined by the configuration of 15-H(p)ETE. 15S-H(p)ETE is the major product of 15-lipoxygenase, whereas 15R-H(p)ETE is generated by either ASA-acetylated PGHS-2 or cytochromes P-450.

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