By Hsian-Rong Tseng, Paul C. Celestre, J. Fraser Stoddart (auth.), Professor Norikazu Ueyama, Professor Akira Harada (eds.)
This e-book offers an in depth account of the synthesis, characterization and alertness of natural and inorganic macromolecular nanostructured fabrics. those fabrics encompass uncomplicated natural compounds, inorganic complexes and polymers, and reveal designated houses equivalent to electric conductivity starting from semiconducting to superconducting. additionally defined within the ebook are the jobs of those fabrics in electrodeposition and fuel deposition, as photosensitizers, magnets, macromolecular steel catalysts, sol-gel hybrids, and in biomineralization. The ebook covers many crucial and well timed matters eager about the synthesis of nanostructured materials.
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Additional info for Macromolecular Nanostructured Materials
Shuttling behavior of the molecular shuttle is solvent- and temperature-sensitive and could be controlled by double interactions : hydrophobic interaction between a cyclodextrin ring and a station and a repulsive interaction between a cyclodextrin ring and a linker. ;, =80 sec - I ,/ (at T,= 130 °Cl '-Fig. 26 Molecul ar shuttle containing a-cyclodextrin. ' This is a new method to control the mobility of a bead in a molecular shuttle. 6 Electronic Trap While we were preparing the molecular shuttle, we found that cationic groups serve as a potential surface for the translocation of a cyclodextrin ring on a polymer chain .
Based on these observations, we decided to make a molecular shuttle in which a cyclodextrin moves back and forth along a chain. 5 Molecular Shuttle We have designed a molecular shuttle as follows : n-cyclcdextrin as a ring, two polymethylene chains as stations, 4,4'-bipyridinum units as linkers, and dinitrophenyl groups as stoppers (Fig. 26). Shuttling behavior of the molecular shuttle is solvent- and temperature-sensitive and could be controlled by double interactions : hydrophobic interaction between a cyclodextrin ring and a station and a repulsive interaction between a cyclodextrin ring and a linker.
Of domains . A CdCh subphase diminished the electrostatic repulsion between the head groups of the DMPA- anions, generating a more uniform thin film of the pseudorotaxane entities . BAM becomes an essential technique for collecting data on the nature of surface domains. It created an informed feedback loop which permits the evaluation of device performance in relation to the interfacial characteri stics of the (supra)molecular switches . The remnant molecular signature of an MSTJ fabricated from the pseudorotaxane [8::>7]4+ is presented in Fig.